CAS
NO. |
583-52-8
(Anhydrous) 6487-48-5 (Monohydrate) 127-96-8 (Dihydrate) |
|
EINECS NO. |
209-506-8 (Anhydrous) 204-874-6
(Dihydrate) |
FORMULA |
K2C2O4·H2O |
MOL
WT. |
184.21 |
H.S.
CODE
|
2917.11.0000 |
TOXICITY
|
|
SYNONYMS |
Oxalic acid
dipotassium salt monohydrate; |
Potassium
oxalate monohydrate; Dikaliumoxalat
(German); Oxalato de dipotasio (Spanish); Oxalate de dipotassium
(French); Dipotassium oxalate monohydrate; |
SMILES |
O.[K+].[K+].[O-]C(=O)C([O-])=O |
CLASSIFICATION
|
Biological Buffer, Chelating agent |
EXTRA
NOTES
|
|
PHYSICAL AND CHEMICAL PROPERTIES
|
PHYSICAL
STATE |
white
crystals |
MELTING POINT |
356 C |
BOILING
POINT |
|
SPECIFIC GRAVITY |
2.13 |
SOLUBILITY
IN WATER |
364 g/l at 20 C |
pH |
7-
8 |
VAPOR DENSITY |
|
AUTOIGNITION
|
|
NFPA
RATINGS
|
Health: 3; Flammability: 1; Reactivity: 0 |
REFRACTIVE
INDEX
|
|
FLASH
POINT |
|
STABILITY |
Stable under ordinary conditions.
Moisture sensitive |
EXTERNAL LINKS
& GENERAL
DESCRIPTION
|
Wikipedia
Linking
Material
Safety Data Sheet
Google
Scholar Search
Drug
Information Portal (U.S. National Library of Medicine) - Potassium
oxalate
PubChem
Compound
Summary
- Potassium oxalate
Local: Oxalic Acid
(also called Ethanedioic Acid) is a colourless, crystalline, toxic organic
compound belonging to the family of dicarboxylic acids; melting at 187 C;
soluble in water, alcohol, and ether. It occurs in the form of its metal salts
(usually calcium or potassium) in many plants. It is commercially manufactured
by heating sodium formate in the presence of an alkali catalyst to form sodium
oxalate, which should be converted to free oxalic acid when treated with
sulfuric acid. It is also prepared by oxidizing carbohydrates with nitric acid,
by heating saw dust with caustic alkalies or by fermentation of sugar solutions
in the presence of certain molds. Oxalic acid is the only possible compound in
which two carboxyl groups are joined directly; for this reason oxalic acid is
one of the strongest acids in organic compounds. Unlike other carboxylic acids,
oxalic acid (and formic acid) is readily oxidized and combine with calcium,
iron, sodium, magnesium, or potassium to form less soluble salts called
oxalates. Oxalic acid and oxalates are useful as reducing agents for
photography, bleaching, and rust removal. They are widely used as an purifying
agent in pharmaceutical industry, precipitating agent in rare-earth metal
processing, bleaching agent in textile and wood industry, rust-remover for metal
treatment, grinding agent, waste water treatment. acid rinse in laundries and
removing scale from automobile radiators.
|
SALES
SPECIFICATION |
APPEARANCE
|
white crystals |
PURITY |
99.0%
min |
CHLORIDE
|
0.01%
max
|
SULFATE
|
0.01%
max
|
HEAVY
METALS
|
10ppm
max
|
IRON
|
10ppm
max
|
INSOLUBLES
|
0.05%
max
|
TRANSPORTATION |
PACKING |
25kgs
in bag |
HAZARD CLASS |
6.1
(Packing Group: III) |
UN
NO. |
2811 |
SAFETY
INFORMATION |
HAZARD OVERVIEW
|
Harmful if absorbed through the skin. Hygroscopic (absorbs moisture
from the air). Harmful if swallowed. May cause kidney damage. Causes
eye, skin, and respiratory tract irritation. Target Organs: Kidneys,
heart, eyes, skin, brain, nerves, mucous membranes.
|
GHS
|
|
SIGNAL WORD |
Warning |
PICTOGRAMS
|
|
HAZARD
STATEMENTS
|
H312 Harmful in contact with skin H302 Harmful
if swallowed
|
PRECAUTIONARY
STATEMENTS
|
P280 Wear protective gloves/protective clothing/eye protection/face
protection P302 + P352 IF ON SKIN: Wash with plenty of
soap and water P301+ P312 IF SWALLOWED: Call a POISON CENTER
or doctor/physician if you feel unwell
|
EC DIRECTIVES |
|
HAZARD
CODES |
|
RISK PHRASES
|
21/22 Harmful in contact with skin and if swallowed.
|
SAFETY
PHRASES
|
24/25: Avoid contact with skin and eyes
|
PRICE
INFORMATION |
|